! Comment line must begin with the symbol ! .
! Any line with : (Headings) MUST begin at the first position of the line.
! All other lines must be indented by one or more spaces.
Boat Rate Calibration:
InchesPerMin 0 3.9 5.0 7.0 8.2 10.0 12.2 15.7 27.5 32.3
Percentage 0 5 6.3 8.5 10 11.5 15 20 30 40
Constants:
boatSpeedSafetyLimit ← 15.0 "/min
maxRampRateUp ← 17/min
! This assumes the ramp up rate in the range of the temperature of interest
! is a constant.
maxRampRateDown ← 12/min
! This assumes the ramp down rate in the range of the temperature of interest
! is a constant.
Gas Flow Calibration:
! The names of the gases could be any symbols except *.
! Flow rate ( Litres per minute )
Gas 0 1 2 3 4 5 6 7 8 9 10
Ar 0 6 13 21 30 41 53 65 77 90 99.99
Fg 0 5 12 20 30 42 54 64 78 89 99.99
H2 0 3 6 10 14 19 23 29 34 39 45.00
N2 0 5 12 20 30 41 54 64 78 89 99.99
O2 0 6 14 22 32 43 56 67 77 89 99.99
PH3 0 5 12 20 29 40 51 64 76 89 99.99
! Flow rate ( cc per minute)
! 0 50 100 150 200 250 300 350 400 450 500
TCA 0 9 19 29 39 49 60 70 80 90 99.99
POCl3 0 9 19 29 39 49 60 70 80 90 99.99
Gas Plumbing:
! Entry for the Gas Flow Controller that is not plumbed should be the symbol, *.
! Gas Flow Controller
! Tube 1 2 3 4 5 6 7
1 TCA O2 H2 Ar N2 * *
2 TCA O2 H2 Ar N2 * *
3 TCA O2 H2 Ar N2 * *
4 TCA O2 H2 Ar N2 * *
5 PoCl3 O2 Ar PH3 N2 * *
6 TCA O2 Ar FG N2 * *
7 Ar O2 H2 TCA N2 FG *
8 Ar O2 H2 TCA N2 FG *
Temperature Calibration:
! Tube Reaction Profile temp Zone 1 Zone 2 Zone 3
1 Dry 800.0 812.0 765.0 776.0
1 Dry 900.0 912.0 866.0 879.0
1 Dry 1000.0 1012.2 968.0 982.3
1 Dry 950.0 930.0 895.0 930.0
1 Dry 1142.0 1126.0 1116.0 1122.0
1 Wet 800.0 783.0 779.0 771.0
1 Wet 850.0 825.0 823.0 826.0
1 Wet 900.0 881.8 878.0 876.3
1 Wet 950.0 931.0 925.0 926.0
1 Wet 1000.0 980.0 975.0 976.0
2 Dry 800.0 779.0 784.0 783.0
2 Dry 900.0 888.0 888.0 888.0
2 Dry 1000.0 988.0 988.8 988.0
2 Dry 1100.0 1086.0 1081.0 1079.0
2 Dry 1142.0 1128.0 1093.0 1110.0
2 Wet 800.0 778.0 783.0 778.0
2 Wet 850.0 828.0 838.0 828.0
2 Wet 900.0 880.5 883.5 878.9
2 Wet 950.0 928.0 938.0 928.0
2 Wet 1000.0 980.0 983.0 978.0
3 Dry 800.0 780.0 724.0 776.0
3 Dry 900.0 880.0 830.0 872.0
3 Dry 1000.0 989.4 935.6 980.0
3 Dry 1100.0 1091.0 1093.0 1098.0
3 Dry 1142.0 1131.0 1133.0 1135.0
3 Wet 800.0 783.0 772.0 780.0
3 Wet 850.0 833.0 820.0 830.0
3 Wet 900.0 887.9 872.6 884.3
3 Wet 950.0 933.0 920.0 930.0
3 Wet 1000.0 987.0 972.0 984.0
4 Dry 800.0 776.8 747.4 775.3
4 Dry 900.0 871.0 845.0 875.0
4 Dry 1000.0 985.0 922.0 985.0
4 Dry 1100.0 1075.0 1028.0 1070.0
4 Dry 1142.0 1117.0 1070.0 1110.0
4 Wet 800.0 776.0 747.0 762.0
4 Wet 850.0 823.0 813.0 829.0
4 Wet 900.0 876.5 847.2 862.3
4 Wet 950.0 923.0 933.0 929.0
4 Wet 1000.0 976.0 947.0 942.0
5 Dry 800.0 790.0 782.0 783.0
5 Dry 900.0 897.0 860.0 887.0
5 Dry 950.0 940.0 928.0 915.0
5 Dry 1000.0 990.0 977.0 983.0
5 Dry 1100.0 1098.0 1070.0 1098.0
6 Dry 400.0 389.0 385.0 385.0
6 Dry 450.0 451.0 427.0 427.0
6 Dry 800.0 783.0 785.0 785.0
6 Dry 900.0 891.0 875.0 878.0
6 Dry 1000.0 953.0 978.0 985.0
7 Dry 800.0 774.0 756.0 782.0
7 Dry 900.0 879.0 852.0 882.0
7 Dry 1000.0 977.0 975.0 979.0
7 Dry 1100.0 1077.0 1075.0 1080.0
7 Dry 600.0 575.0 566.0 578.0
7 Wet 800.0 777.0 745.0 780.0
7 Wet 850.0 827.0 795.0 830.0
7 Wet 900.0 880.0 855.0 880.0
7 Wet 950.0 927.0 895.0 930.0
7 Wet 1000.0 980.0 955.0 980.0
8 Dry 800.0 780.0 769.0 768.0
8 Dry 350.0 316.0 310.0 310.0
8 Dry 950.0 935.0 927.0 923.0
8 Dry 1000.0 987.0 979.0 978.0
8 Dry 450.0 390.0 392.0 391.0
8 Wet 800.0 768.0 742.0 770.0
8 Wet 850.0 818.0 792.0 820.0
8 Wet 900.0 868.0 842.0 870.0
8 Wet 950.0 918.0 892.0 920.0
8 Wet 1000.0 968.0 942.0 970.0
Idle Conditions:
! Tube Idle Conditions
1 dry 800C O2 @ 4.0 l/m
2 dry 800C O2 @ 4.0 l/m
3 dry 800C O2 @ 4.0 l/m
4 dry 800C O2 @ 4.0 l/m
5 dry 900C N2 @ 4.0 l/m + O2 @ 1.0 l/m
6 dry 450C Ar @ 4.0 l/m
7 dry 800C O2 @ 4.0 l/m
8 dry 450C Ar @ 5.0 l/m